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Molecular Design to Improve the Performance of Donor-p Acceptor Near-IR Organic Dye-Sensitized Solar Cells

Release Time:2019-03-09  Hits:

Indexed by: Journal Article

Date of Publication: 2011-11-18

Journal: CHEMSUSCHEM

Included Journals: Scopus、EI、PubMed、SCIE

Volume: 4

Issue: 11

Page Number: 1601-1605

ISSN: 1864-5631

Key Words: aggregation; dyes; photophysics; sensitizers; solar cells

Abstract: Near-dye experience: Long, flexible carbon chains in the lateral anchoring groups of the donor part of a donor-π acceptor organic dye increase the power conversion efficiency dramatically. This performance enhancement can be ascribed to the prevention of the formation of molecular aggregates on the semiconductor nanoparticles, resulting in a lower recombination rate between transported electrons and I3-ions. A cell based on the new dye, HY113, gives a maximum IPCE value of 93% at 660nm. Copyright © 2011 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.

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