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Indexed by:期刊论文

Date of Publication:2018-12-01

Journal:JOURNAL OF COLLOID AND INTERFACE SCIENCE

Included Journals:SCIE

Volume:531

Page Number:91-97

ISSN No.:0021-9797

Key Words:Ammonia; In-situ FTIR; MnCeZrOx mixed oxides; NOx; Reaction mechanisms; Selective catalytic reduction

Abstract:A series of MnCeZrOx mixed oxide catalysts were facilely synthesized using the impregnation-NH3 center dot H2O coprecipitation method and tested for selective catalytic reduction (SCR) of NO with NH3. Doping manganese significantly improved the catalytic activity and the best performing SCR catalyst, Mn0.25Ce0.5Zr0.25Ox, was shown to achieve NO conversion > 80% in the temperature range (60-350 degrees C), with the denitration effect up to 50% at room temperature (conditions: [NO] = [NH3] = 500 PPM [O-2] = 5 vol%, He as balance, flow rate = 100 mL/min, GHSV = 40, 000 h(-1)). Characterization of the catalyst using BET, XRD, XPS, H-2-TPR, and in-situ FTIR proved that the improved SCR activity may be attributed to the large surface area, great reduction ability and increased amount of surface adsorbed oxygen afforded by the introduction of manganese. The SCR reaction mechanisms were also investigated by analyzing in-situ FTIR spectra and the SCR reaction pathway over the Mn0.25Ce0.5Zr0.25Ox catalyst was shown to mostly follow the E-R mechanism. (C) 2018 Elsevier Inc. All rights reserved.