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A novel approach to synthesize ultrasmall Cu doped Zn-In-Se nanocrystal emitters in a colloidal system

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Indexed by:期刊论文

Date of Publication:2014-03-21

Journal:NANOSCALE

Included Journals:SCIE、EI、PubMed、Scopus

Volume:6

Issue:6

Page Number:3403-3409

ISSN No.:2040-3364

Abstract:A facile phosphine-free approach is presented to prepare Cu doped ternary Zn-In-Se nanocrystals with high performance photoluminescence. By doping during nucleation stage, Cu dopant serving as a dominative emission centre was introduced into a weak fluorescence ternary system to modify the emission path. As a result of varying the ratios of zinc to indium, emission of the products is tunable ranging from 620 to 545 nm and a photoluminescence quantum yield of up to 20%. Meanwhile, a large Stokes shift of 467 meV is achieved.

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