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Synthesis and photo-catalytic degradation property of nano structured-ZnO with different morphology

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Indexed by: Journal Article

Date of Publication: 2008-06-15

Journal: MATERIALS LETTERS

Included Journals: EI、SCIE

Volume: 62

Issue: 16

Page Number: 2359-2362

ISSN: 0167-577X

Key Words: ZnO; nanomaterials; semiconductor; catalysts

Abstract: ZnO nanostructures with different morphology have been successfully fabricated by a simple relative low temperature approach at 90 degrees C for 5 h without surfactant assistance. These structures can be easily tailed using varied concentrations of sodium hydroxide (NaOH) and different amounts of the hydrazine hydrate (N(2)H(4)center dot H(2)O). X-ray diffraction (XRD) result proves the formation of ZnO with wurtzite structure. Microstructure as revealed by scanning electron microscopy (SEM) and transmission electron microscopy (TEM) indicates that the rod-like and chrysanthemum-like ZnO nanostructures contain many radial nanorods, which grow along the [0001] direction. Furthermore, the as-prepared ZnO nanomaterials exhibit high activity on the photo-catalytic degradation of typical persistent organic pollutants (POPs), indicating that they are promising as semiconductor photo-catalysts. (C) 2007 Elsevier B.V. All rights reserved.

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