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Selective oxidation of cyclopentene catalyzed by Pd(CH3COO)(2)-NPMoV tinder oxygen atmosphere

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Indexed by:期刊论文

Date of Publication:2008-09-01

Journal:REACTION KINETICS AND CATALYSIS LETTERS

Included Journals:EI、SCIE、Scopus

Volume:94

Issue:2

Page Number:191-198

ISSN No.:0133-1736

Key Words:cyclopentene; cyclopnetanone; Pd(CH3COO)(2); NPMoV

Abstract:The selective oxidation of cyclopentene to cyclopentanone catalyzed by Pd(CH3COO)(2)-NPMoV was investigated under atmospheric oxygen in aqueous acetonitrile acidified by CH3SO3H. It was shown that the conversion of cyclopentene and the yield of cyclopentanone was nearly 100% and 94.6%, respectively, under the optimized reaction condition.

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