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Pt-free, non-thermal plasma-assisted NOx storage and reduction over M/Ba/Al2O3 (M = Mn, Fe, Co, Ni, Cu) catalysts

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Indexed by:期刊论文

Date of Publication:2015-11-01

Journal:2nd China-USA Symposium on Energy

Included Journals:SCIE、CPCI-S、Scopus

Volume:256

Issue:P1

Page Number:115-123

ISSN No.:0920-5861

Key Words:Transition metal oxide; NOx storage-reduction; LNT catalyst; Non thermal plasma

Abstract:Based on their high NOx storage capacities (NSCs), a series of M/Ba/Al (M = Mn, Fe, Co, Ni, Cu) catalysts were evaluated in NOx storage-reduction catalysis. Although the M/Ba/Al catalysts exhibited high NSC values, they exhibited much lower activity during lean-rich cycling compared with a traditional Pt/Ba/Al catalyst, indicating that regeneration of stored NOx is the rate limiting step for the M/Ba/Al samples. By employing an H-2-plasma in the rich phase to assist reduction of the stored NOx, the NOx conversion was greatly improved, especially at low temperature. (C) 2015 Elsevier B.V. All rights reserved.

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