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Indexed by:期刊论文
Date of Publication:2018-04-01
Journal:CHINESE JOURNAL OF CHEMISTRY
Included Journals:SCIE、Scopus
Volume:36
Issue:4
Page Number:329-332
ISSN No.:1001-604X
Key Words:solid reduction; subnanometer-sized clusters; gold catalysts; CO2 hydrogenation
Abstract:An effective solvent-free method based on a solid-reduction process was developed to fabricate ultrafine gold catalysts. By this method we revealed a strong size-dependent activity of Au species in which subnanometer-sized clusters exhibited the best activity in the hydrogenation of CO2 to formate, with a turnover number of up to 9278 over 7 h at 90 degrees C.