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论文类型：期刊论文

发表时间：2008-11-15

发表刊物：MATERIALS LETTERS

收录刊物：SCIE

卷号：62

期号：28

页面范围：4366-4368

ISSN号：0167-577X

关键字：nanomaterials; powder technology; two-phase; silver nanoparticles

摘要：Nearly monodisperse silver nanoparticles were prepared in a two-phase water-cyclohexane system. Aqueous silver nitrate was reduced by the product of the reaction of aqueous hydrazine with benzyl aldehyde in cyclohexane to form, in the presence of oleic acid, cyclohexane-soluble silver nanoparticles. The silver nanoparticles were examined by transmission electron microscopy (TEM), UV-visible spectroscopy (UV-vis). X-ray diffraction (XRD), and Fourier transform infrared spectroscopy (FT-IR). The nanoparticles are relatively monodisperse (diameter less than 6 nm) and have good stability in cyclohexane due to the oleic acid adsorbed on their surfaces. These silver nanoparticles were successfully assembled into a powder with a face-centered-cubic structure by slow evaporation of the solvent. With some change in particle size, these silver nanoparticles could be transferred from cyclohexane to water by the addition of cetyltrimethylammonium bromide. (C) 2008 Elsevier B.V. All rights reserved.