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Boron Removal from Metallurgical Silicon using Si-Al-Sn Ternary Alloy

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Indexed by:期刊论文

Date of Publication:2014-01-22

Journal:SEPARATION SCIENCE AND TECHNOLOGY

Included Journals:SCIE、EI

Volume:49

Issue:2

Page Number:305-310

ISSN No.:0149-6395

Key Words:alloy refining; segregation coefficient; Si-Al-Sn alloy; solar-grade silicon

Abstract:Numerous studies have searched for methods of Si refining for the production of photovoltaic cells to alleviate the global shortage of solar-grade Si. An alloy refining progress with a Si-Al-Sn melt was developed in this paper. To elucidate the relationship between Sn and B, the interaction parameter between them at 1173K was determined as 2506 +/- 143. This result indicated the strongly repulsive force between Sn and B. Thermodynamic analysis and experiments showed that the purification efficiency of Si-Al-Sn alloy weakened with increased Sn content in the melt.

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