点击次数：

发布时间：2019-03-09

论文类型：期刊论文

发表时间：2010-05-01

发表刊物：MATERIALS RESEARCH BULLETIN

收录刊物：EI、SCIE

卷号：45

期号：5

页面范围：519-522

ISSN号：0025-5408

关键字：Nanostructures; High pressure; Raman spectroscopy; X-ray diffraction; Magnetic properties

摘要：Carbon-coated iron nanoparticles were synthesized by detonating a mixture of ferrocene, naphthalene and hexahydro-1,3,5-trinitro-1,3,5-triazine (RDX) in an explosion vessel under low vacuum conditions (8.1 kPa). The RDX functioned as an energy source for the decomposition of ferrocene and naphthalene. The carbon-coated iron nanoparticles were formed as soot-like deposits on the inner surface of the reactor, which were characterized by XRD, TEM, HRTEM, Raman spectroscopy and vibrating sample magnetometer. And a portion of the detonation soot was treated with hydrochloric acid. The product was carbon-coated nanoparticles in perfect core-shell structures with graphitic shells and bcc-Fe cores. The detonation technique offers an energy-saving route to the synthesis of carbon-coated nanomaterials. (C) 2010 Elsevier Ltd. All rights reserved.