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个人信息Personal Information
副教授
博士生导师
硕士生导师
性别：男
毕业院校：香港中文大学
学位：博士
所在单位：化工学院
学科：有机化学
办公地点：大连理工大学西校区，E-308
电子邮箱：liujh@dlut.edu.cn
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A Suzuki-type cross-coupling reaction of arylacetylene halides with arylboronic acids
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论文类型：期刊论文
发表时间：2011-07-01
发表刊物：APPLIED ORGANOMETALLIC CHEMISTRY
收录刊物：SCIE、EI
卷号：25
期号：7
页面范围：514-520
ISSN号：0268-2605
关键字：Suzuki cross-coupling; diarylacetylene; palladium chloride; alkynylation
摘要：A PdCl2-catalyzed direct alkynylation of arylboronic acids to give diarylacetylenes is described. The optimal conditions using PdCl2 as catalyst, MeOH-PhMe-H2O as solvent and K2CO3 as base effectively suppressed the formation of homo-coupling product and afforded moderate to good yield of the desired unsymmetrical coupling product. This reaction represents a Suzuki-type sp(2)(C-B)-sp(C-X) cross-coupling. Copyright (C) 2011 John Wiley & Sons, Ltd.