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论文类型：期刊论文

发表时间：2018-05-15

发表刊物：MICROPOROUS AND MESOPOROUS MATERIALS

收录刊物：SCIE、EI

卷号：262

页面范围：199-206

ISSN号：1387-1811

关键字：V2O3@C core-shell nanorods; Porous structures; Amorphous carbon; Large specific surface area; Supercapacitor electrode; Device

摘要：V2O3@C core-shell nanorods with porous structures and large specific surface area were synthesized using V2O5 nanowires as the source of core and glucose as the source of shell by a facile hydrothermal route combination of heat treatment. As-prepared V2O3@C nanorods comprised of core-shell structures with crystalline V2O3 cores and amorphous carbon shells. Nitrogen adsorption-desorption isotherms revealed that V2O3@C core-shell nanorods displayed BET specific surface area as high as 219 m(2).g(-1) and had hierarchical porous structures. Electrochemical properties of V2O3@C core-shell nanorods as supercapacitor electrode were studied and showed their measured capacitance was based on the pseudocapacitance. Specific capacitances of V2O3@C core-shell nanorods measured 228, 221, 207, 158 and 127 F.g(-1) at current densities of 0.5, 1, 2, 5 and 10 kg(-1), respectively. Results showed V2O3@C core-shell nanorods displayed higher specific capacitance than values of carbon spheres (4 F.g(-1) at 1 kg(-1)) and V2O3 nanomaterials (49 F.g(-1) at 1 kg(-1)), Asymmetric supercapacitor device assembled from V2O3@C core-shell nanorods and activated carbon (V2O3@C//C) showed specific capacitances of 0.297, 0.274, 0.230, 0.194 and 0.169 F.cm(-2) at current densities of 0.5, 1, 2, 5 and 10 mA.cm(-2), respectively. It showed higher specific capacitance than that of V2O3//C device (0.219 F.cm(-2) at 1 mA.cm(-2)). A capacitance retention of 86% for V2O3@C//C device after 1000 cycles indicated that V2O3@C had good cycling performance for supercapacitor application. Present findings suggested that V2O3@C core-shell nanorods could be considered as potential materials for high-performance energy storage materials.