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论文类型：期刊论文

发表时间：2016-06-01

发表刊物：CHEMOSPHERE

收录刊物：SCIE、EI、PubMed

卷号：153

页面范围：494-499

ISSN号：0045-6535

关键字：Benzophenone-3; Metabolites; Photodegradation; Triplet-excited dissolved organic matter; Hydroxyl radical

摘要：The occurrence of sunscreen agents and their metabolites in surface waters gives rise to public concerns. However, little is known about the environmental fate of these pollutants at present, especially for their metabolites. In this study, we investigated the photochemical of sunscreen agents and their metabolites in natural waters, adopting benzophenone-3 (BP-3) and its human metabolite 4-hydroxybenzophenone (4-OH-BP3) as examples. Results show that only anionic forms of both BP-3 and 4-OH-BP3 can undergo direct photodegradation. The photolytic rates of both compounds in natural waters are faster as compared to those in pure water. Radical scavenging experiments revealed that triplet-excited dissolved organic matter ((DOM)-D-3*) was responsible for the indirect photodegradation of BP-3 and 4-OH-BP3 in seawater, whereas in freshwater, the indirect photodegradation of these two compounds was attributed to (DOM)-D-3* and center dot OH. 102 plays a negligible role in their photodegradation because of the weak 102 reactivity. Furthermore, we probed the contribution of center dot OH and (DOM)-D-3* to the photodegradation of both compounds in freshwater, and the results revealed that center dot OH accounted for 56% and 59% of the observed photodegradation for BP-3 and 4-OH-BP3, respectively, whereas (DOM)-D-3* accounted for 43% and 12% of the observed photodegradation for BP-3 and 4-OH-BP3, respectively. These results are helpful in assessing the ecological risk of BP-3 and its metabolite in the aquatic environment. (C) 2016 Elsevier Ltd. All rights reserved.