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论文类型：期刊论文

发表时间：2014-11-03

发表刊物：CHEMISTRY-A EUROPEAN JOURNAL

收录刊物：SCIE、EI、PubMed、Scopus

卷号：20

期号：45

页面范围：14763-14770

ISSN号：0947-6539

关键字：doping; nanosheets; photochemistry; plasma chemistry; titanium; UV; Vis spectroscopy

摘要：Anatase TiO2 nanosheets with exposed {001} facets have been controllably modified under non-thermal dielectric barrier discharge (DBD) plasma with various working gas, including Ar, H-2, and NH3. The obtained TiO2 nanosheets possess a unique crystalline core/amorphous shell structure (TiO2@TiO2-x), which exhibit the improved visible and near-infrared light absorption. The types of dopants (oxygen vacancy/surface Ti3+/substituted N) in oxygen-deficient TiO2 can be tuned by controlling the working gases during plasma discharge. Both surface Ti3+ and substituted N were doped into the lattice of TiO2 through NH3 plasma discharge, whereas the oxygen vacancy or Ti3+ (along with the oxygen vacancy) was obtained after Ar or H-2 plasma treatment. The TiO2@TiO2-x from NH3 plasma with a green color shows the highest photocatalytic activity under visible-light irradiation compared with the products from Ar plasma or H-2 plasma due to the synergistic effect of reduction and simultaneous nitridation in the NH3 plasma.