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论文类型：期刊论文

发表时间：2017-01-01

发表刊物：JOURNAL OF CO2 UTILIZATION

收录刊物：Scopus、EI、SCIE

卷号：17

页面范围：162-169

ISSN号：2212-9820

关键字：Flower-like alumina; Iron oxide; Ethylbenzene dehydrogenation; Carbon dioxide

摘要：An Al2O3 support with flower-like morphology was used as the support of iron oxide catalyst for oxidative dehydrogenation of ethylbenzene with CO2. A commercial Al2O3 was also used for comparison. These catalyst materials were characterized by X-ray diffraction (XRD), field emission scanning electron microscopy (FESEM), transmission electron microscopy (TEM), N-2 physisorption, H-2 temperature programmed reduction (H-2-TPR), cyclic voltammetry (CV), electron paramagnetic resonance (EPR), X-ray photoelectron spectroscopy (XPS) and CO2 temperature programmed desorption (CO2-TPD) techniques. It was found that the concentration of O-2-anions on the flower-like Al2O3 surface was significantly higher than that on the commercial Al2O3 surface, leading to large amounts of highly dispersed FexOy clusters on flower-like Al2O3 in contrast with large Fe2O3 particles mainly present on commercial Al2O3. A possible formation mechanism of the small FexOy clusters was proposed. The catalytic results indicated that the highly dispersed FexOy clusters possessed an excellent catalytic activity, since the ethylbenzene conversion over Fe2O3/flower-like Al2O3 was 1.6 times higher than that over Fe2O3/commercial Al2O3. This work provides a new route for designing supported iron catalysts that are widely used, and flowerlike Al2O3 is expected to be a promising catalyst support for oxidative dehydrogenation of ethylbenzene with CO2. (C) 2016 Elsevier Ltd. All rights reserved.