Indexed by:期刊论文

Date of Publication:2016-12-01

Journal:MICROPOROUS AND MESOPOROUS MATERIALS

Included Journals:SCIE、EI、Scopus

Volume:236

Page Number:211-217

ISSN No.:1387-1811

Key Words:Al-rich Beta; Cu-Fe-Beta; NH3-SCR; Synergistic effect; Sulfur resistance

Abstract:Copper and iron bimetal modified Al-rich Beta zeolites from template-free synthesis were prepared for selective catalytic reduction (SCR) of NOX with NH3 in exhaust gas streams. Comparing to the Cu-based and Fe-based mono-component Beta catalysts, Cu(3.0)-Fe(1.3)-Beta bi-component catalyst shows better low-temperature activity and wider reaction-temperature window. Over 80% of NO conversion can be achieved at the temperature region of 125-500 degrees C. Due to the synergistic effect of copper and iron evidenced by XRD, UV-Vis-NIR, EPR and XPS measurements, the dispersion state of active components as well as the ratio of Cu2+/Cu+ and Fe3+/Fe2+ were improved over Cu(3.0)-Fe(1.3)-Beta. Isolated Cu2+ and Fe3+ ions which located at the exchange sites could be the active species at the low-temperature region, while FeOX cluster species may be more important to the high-temperature activity. During the test of sulfur resistance, Fe-containing samples including Cu(3.0)-Fe(1.3)-Beta and Fe(2.7)-Beta-4 present better performance compared to Cu(4.1)-Beta-4. Deactivation of Cu-based catalyst is attributed to the easier deposition of sulfates over the surface according to the results of TGA coupled with TPD experiments. (C) 2016 Elsevier Inc. All rights reserved.