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Indexed by:期刊论文

Date of Publication:2009-03-20

Journal:JOURNAL OF ALLOYS AND COMPOUNDS

Included Journals:SCIE、EI

Volume:472

Issue:1-2

Page Number:525-529

ISSN No.:0925-8388

Key Words:Intermetallics; Diffusion; Kinetics; Microstructure; High magnetic fields

Abstract:The effect of a 12T high magnetic field on the intermetallic phase growth in Ni-Al diffusion couples was studied in this paper. It was found that Ni(2)Al(3) and NiAl(3) formed in the couples prepared by the pouring technique. After annealing with or without the magnetic field, the diffusion zones were still composed of Ni(2)Al(3) and NiAl(3). The thickness of each intermetallic layer was also examined. The results demonstrate that the magnetic field reduces the thickness of Ni(2)Al(3) and NiAl(3) layers. This reduction of intermetallic layer thickness can be attributed to the decreasing frequency factor under the magnetic field. However, the activation energy for layer growth is independent of the application of the magnetic field. The magnetic field direction has an effect on the layer growth of the Ni(2)Al(3) and NiAl(3), which might result from the change of the probability of the atomic jump in the magnetic field direction. The decrease of the layer thickness suggests that the diffusion of atoms is retarded under the magnetic field. This retardation was explained based on the ambipolar diffusion theory. (C) 2008 Elsevier B.V. All rights reserved.