Iron-catalyzed boration of allylic alcohols with H3BO3 as an additive
Release Time:2019-03-12 Hits:
Indexed by: Journal Article
Date of Publication: 2018-01-01
Journal: SYNTHETIC COMMUNICATIONS
Included Journals: SCIE
Volume: 48
Issue: 7
Page Number: 795-801
ISSN: 0039-7911
Key Words: Allylboronates; allylic alcohols; boration; boric acid; iron-catalysis
Abstract: A method for the synthesis of allylboronates by iron-catalyzed boration of allylic alcohols with H3BO3 as an additive is developed. The introduction of H3BO3 promotes the cleavage of CO bond in allylic alcohols obviously. Functional groups, such as fluoro, chloro, bromo, alkyl, and alkoxy, are tolerated well. Thus, various allylboronates are obtained in acceptable yield.
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