NAME

曲景平

Paper Publications

Asymmetric [3+2] cycloaddition of 3-amino oxindole-based azomethine ylides with alpha,beta-ynones: a straightforward approach to spirooxindoles incorporating 2,5-dihydropyrroles and pyrroles
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  • Indexed by:

    Journal Papers

  • First Author:

    Zhu, Guodong

  • Correspondence Author:

    Wang, BM (reprint author), Dalian Univ Technol, Sch Pharmaceut Sci & Technol, State Key Lab Fine Chem, Dalian 116024, Peoples R China.

  • Co-author:

    Wu, Shiqi,Bao, Xiaoze,Cui, Longchen,Zhang, Yanpeng,Qu, Jingping,Chen, Hongbo,Wang, Baomin

  • Date of Publication:

    2017-04-30

  • Journal:

    CHEMICAL COMMUNICATIONS

  • Included Journals:

    SCIE、PubMed

  • Document Type:

    J

  • Volume:

    53

  • Issue:

    34

  • Page Number:

    4714-4717

  • ISSN No.:

    1359-7345

  • Abstract:

    An organocatalytic asymmetric [3+2] cycloaddition of 3-amino oxindole-based azomethine ylides and alpha,beta-ynones has been developed. This reaction afforded spiro[dihydropyrrole-2,3'-oxindole] products in high chemical yields with excellent stereoselectivities (up to 99% yields, 420 : 1 dr and > 99% ee). Notably, a series of important spiro[pyrrole-oxindole] derivatives were readily obtained via oxidation of the cycloadducts, thus extending the diversity of the products.

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