location: Current position: Home >> Scientific Research >> Paper Publications

Synthesis of gem-Difluoroallylboronates via FeCl2-Catalyzed Boration/beta-Fluorine Elimination of Trifluoromethyl Alkenes

Hits:

Indexed by:期刊论文

Date of Publication:2017-02-17

Journal:ORGANIC LETTERS

Included Journals:SCIE、PubMed

Volume:19

Issue:4

Page Number:946-949

ISSN No.:1523-7060

Abstract:The first ferrous chloride catalyzed boration/beta-fluorine elimination of trifluoromethyl alkenes is described. Thus, a full range of gem-difluoroallylboronates were obtained in high yield under mild conditions. As an important fluorinated building block, gem-difluoroallylboronate can be readily converted into diverse difluoro-substituted species.

Pre One:Mechanistic Insights into the Copper-Cocatalyzed Sonogashira Cross-Coupling Reaction: Key Role of an Anion

Next One:Graphene-Based Metal/Acid Bifunctional Catalyst for the Conversion of Levulinic Acid to gamma-Valerolactone