Release Time:2019-03-09  Hits:

Indexed by: Journal Article

Date of Publication: 2015-09-07

Journal: DALTON TRANSACTIONS

Included Journals: Scopus、PubMed、EI、SCIE

Volume: 44

Issue: 33

Page Number: 14952-14958

ISSN: 1477-9226

Abstract: A series of novel carboxylate-bridged cyclopentadienyl diiron complexes [Cp*Fe(mu-SEt)(2)(mu-eta(2)-OOCR)-FeCp*][PF6] (2, R = H; 3, R = Me; 4, R = Et; 5, R = Pr-n; 6, R = Ph; 7, R = p-Me-C6H4; 8, R = PhCH=CH; 9, CH  C) were obtained from alcohols/aldehydes or sodium carboxylates at room temperature. These eight complexes were fully characterized by spectroscopy, and some of them (3, 4, 7 and 8) were further studied by X-ray crystallography. In addition, the electrochemical properties of clusters 2 and 6 are also discussed.