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个人信息Personal Information
教授
博士生导师
硕士生导师
性别：男
毕业院校：日本东京大学
学位：博士
所在单位：化工学院
电子邮箱：qujp@dlut.edu.cn
Iron-catalyzed boration of allylic alcohols with H3BO3 as an additive
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论文类型：期刊论文
发表时间：2018-01-01
发表刊物：SYNTHETIC COMMUNICATIONS
收录刊物：SCIE
卷号：48
期号：7
页面范围：795-801
ISSN号：0039-7911
关键字：Allylboronates; allylic alcohols; boration; boric acid; iron-catalysis
摘要：A method for the synthesis of allylboronates by iron-catalyzed boration of allylic alcohols with H3BO3 as an additive is developed. The introduction of H3BO3 promotes the cleavage of CO bond in allylic alcohols obviously. Functional groups, such as fluoro, chloro, bromo, alkyl, and alkoxy, are tolerated well. Thus, various allylboronates are obtained in acceptable yield.
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