Iron-catalyzed boration of allylic esters: an efficient approach to allylic boronates
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论文类型：期刊论文
发表时间：2017-08-01
发表刊物：ORGANIC CHEMISTRY FRONTIERS
收录刊物：Scopus、SCIE
卷号：4
期号：8
页面范围：1580-1585
ISSN号：2052-4129
摘要：An efficient approach to allylic boronates via iron-catalyzed boration of allylic esters is described. The reactions of allylic esters and bis(pinacolato) diboron (B(2)pin(2)) proceed smoothly catalyzed by FeCl2/PPh3. Thus, a wide range of allylic boronates with broad functional-group compatibility are obtained.