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个人信息Personal Information
教授
博士生导师
硕士生导师
性别：男
毕业院校：日本东京大学
学位：博士
所在单位：化工学院
电子邮箱：qujp@dlut.edu.cn
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Synthesis of gem-Difluoroallylboronates via FeCl2-Catalyzed Boration/beta-Fluorine Elimination of Trifluoromethyl Alkenes
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论文类型：期刊论文
发表时间：2017-02-17
发表刊物：ORGANIC LETTERS
收录刊物：SCIE、PubMed
卷号：19
期号：4
页面范围：946-949
ISSN号：1523-7060
摘要：The first ferrous chloride catalyzed boration/beta-fluorine elimination of trifluoromethyl alkenes is described. Thus, a full range of gem-difluoroallylboronates were obtained in high yield under mild conditions. As an important fluorinated building block, gem-difluoroallylboronate can be readily converted into diverse difluoro-substituted species.