Synthesis of gem-Difluoroallylboronates via FeCl2-Catalyzed Boration/beta-Fluorine Elimination of Trifluoromethyl Alkenes
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论文类型:期刊论文
发表时间:2017-02-17
发表刊物:ORGANIC LETTERS
收录刊物:PubMed、SCIE
卷号:19
期号:4
页面范围:946-949
ISSN号:1523-7060
摘要:The first ferrous chloride catalyzed boration/beta-fluorine elimination of trifluoromethyl alkenes is described. Thus, a full range of gem-difluoroallylboronates were obtained in high yield under mild conditions. As an important fluorinated building block, gem-difluoroallylboronate can be readily converted into diverse difluoro-substituted species.
