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论文类型：期刊论文

发表时间：2015-09-07

发表刊物：DALTON TRANSACTIONS

收录刊物：SCIE、EI、PubMed、Scopus

卷号：44

期号：33

页面范围：14952-14958

ISSN号：1477-9226

摘要：A series of novel carboxylate-bridged cyclopentadienyl diiron complexes [Cp*Fe(mu-SEt)(2)(mu-eta(2)-OOCR)-FeCp*][PF6] (2, R = H; 3, R = Me; 4, R = Et; 5, R = Pr-n; 6, R = Ph; 7, R = p-Me-C6H4; 8, R = PhCH=CH; 9, CH  C) were obtained from alcohols/aldehydes or sodium carboxylates at room temperature. These eight complexes were fully characterized by spectroscopy, and some of them (3, 4, 7 and 8) were further studied by X-ray crystallography. In addition, the electrochemical properties of clusters 2 and 6 are also discussed.