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个人信息Personal Information
教授
博士生导师
硕士生导师
性别：男
毕业院校：日本东京大学
学位：博士
所在单位：化工学院
电子邮箱：qujp@dlut.edu.cn
扫描关注
Development of Tartaric Acid Derived Chiral Guanidines and Their Application to Catalytic Enantioselective alpha-Hydroxylation of beta-Dicarbonyl Compounds
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论文类型：期刊论文
发表时间：2013-06-21
发表刊物：ORGANIC LETTERS
收录刊物：SCIE、PubMed、Scopus
卷号：15
期号：12
页面范围：3106-3109
ISSN号：1523-7060
摘要：A novel library of chiral guanidines featuring a tartaric acid skeleton was developed from diethyl L-tartrate. These guanidines are easily accessed with tunable style and electronic properties. The utilities of the guanidines were highlighted by their ability to catalyze the alpha-hydroxylation of beta-ketoesters and beta-diketones with remarkable efficiency and excellent enantioselectivity.