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个人信息Personal Information
教授
博士生导师
硕士生导师
性别：男
毕业院校：日本东京大学
学位：博士
所在单位：化工学院
电子邮箱：qujp@dlut.edu.cn
Synthesis, structure and reactions of triply selenolate-bridged diiron complex [Cp*Fe(mu-SeMe)(3)FeCp*]
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论文类型：期刊论文
发表时间：2013-03-01
发表刊物：INORGANIC CHEMISTRY COMMUNICATIONS
收录刊物：SCIE
卷号：29
页面范围：179-182
ISSN号：1387-7003
关键字：Iron-selenolate complex; Oxidative addition reaction; Cubane cluster; Crystal structures
摘要：Two new iron-selenolate complexes [Cp*Fe(mu-SeMe)(3)FeCp*] (Cp* = eta(5)-C5Me5) (1) and [Cp*Fe(mu-SeMe)(3-)FeCp*][FeCl3] (2) were prepared by the oxidative addition reaction of MeSeSeMe with [Cp*FeCl](2) in 25% and 20% yields, respectively. In refluxing toluene, the methyl groups in the selenolate ligands of complex 1 were removed, affording a cubane cluster [Cp*4Fe4Se4] (3) in 50% yield. Complex 1 was oxidized by HBF4 to give [Cp*Fe(mu-SeMe)(3)FeCp*][BF4] (4), and the reverse reduction reaction occurred in the presence of CoCp2. (c) 2013 Elsevier B.V. All rights reserved.