Friedel-Crafts-Type Allylation of Nitrogen-Containing Aromatic Compounds with Allylic Alcohols Catalyzed by a [Mo3S4Pd(eta(3)-allyl)] Cluster
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论文类型：期刊论文
发表时间：2012-03-16
发表刊物：JOURNAL OF ORGANIC CHEMISTRY
收录刊物：Scopus、EI、SCIE、PubMed
卷号：77
期号：6
页面范围：2942-2946
ISSN号：0022-3263
摘要：With the direct use of allylic alcohols as allylating agents, the Friedel Crafts-type allylic alkylation of nitrogen-containing aromatic compounds catalyzed by a [Mo3S4Pd(eta(3)-allyl)] cluster is achieved. With a 3 mol % catalyst loading in acetonitrile at re lux or 60 degrees C, a variety of N,N-dialkylanilines and indoles reacted smoothly with allylic alcohols to afford the Friedel-Crafts-type allylation products in good to excellent yields with high levels of regioselectivity.