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个人信息Personal Information
教授
博士生导师
硕士生导师
性别：男
毕业院校：日本东京大学
学位：博士
所在单位：化工学院
电子邮箱：qujp@dlut.edu.cn
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Unusual Thiolate-Bridged Diiron Clusters Bearing the cis-HN = NH Ligand and Their Reactivities with Terminal Alkynes
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论文类型：期刊论文
发表时间：2011-02-09
发表刊物：JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
收录刊物：Scopus、SCIE、EI、PubMed
卷号：133
期号：5
页面范围：1147-1149
ISSN号：0002-7863
摘要：A series of well-defined thiolate-bridged diiron clusters bearing the cis-HN = NH ligand, [Cp(+)Fe(mu-SEt)(2)-(mu-eta(1):eta(1)-HN = NH)FeCp(+)][PF(6)] (Cp(+) = eta(5)-C(5)Me(4)H or eta(5)-C(5)Me(5)), are successfully prepared in high yields and fully characterized by spectroscopy and X-ray crystallography. Under moderate conditions, these new Fe/S clusters exhibit high activity, not only for the catalytic cleavage of the N-N bond of hydrazines but also for the activation and coupling of terminal alkynes.