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论文类型：期刊论文

发表时间：2012-10-28

发表刊物：RSC ADVANCES

收录刊物：SCIE、EI、Scopus

卷号：2

期号：26

页面范围：10085-10090

ISSN号：2046-2069

摘要：Novel rare earth-coordinated polymers were prepared using carboxyl-containing polyaryletherketone (PEK) as the macromolecular ligand and 8-hydroxyquinoline (HQ) as the co-ligand to coordinate with erbium (Er3+), neodymium (Nd3+) and ytterbium (Yb3+), respectively. The FTIR, elemental analysis, inductively coupled plasma, and UV-vis results confirm that the rare earth ions have been attached to the polymer backbone via a coordination bond. The complexes can emit the characteristic near-infrared fluorescence of the corresponding rare earth ions. Moreover, it is found that the synergistic effect of PEK and HQ can significantly enhance the emission intensities. In particular, for PEK-Er3+-HQ, the full width at half maximum (FWHM) of the I-4(13/2)-> I-4(15/2) transition is up to 78 nm. The combination of strong fluorescence emission in the near-infrared range, high glass transition temperature and wide gain bandwidth provides promising potential for optical amplification applications.