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论文类型：期刊论文

发表时间：2011-06-21

发表刊物：SOFT MATTER

收录刊物：Scopus、SCIE、EI

卷号：7

期号：12

页面范围：5723-5730

ISSN号：1744-683X

摘要：Four new polyimide networks were prepared via a one-step polycondensation method by using tris (4-aminophenyl) amine and 1,3,5-tris(4-aminophenyl) benzene to react with pyromellitic dianhydride (PMDA) and naphthalene-1,4,5,8-tetracarboxylic dianhydride (NTDA), respectively. It was found that the topological structures and pore morphologies of the networks were tightly related to the geometrical shape of the net nodes, the molecular volume of the connecting struts, the reactivity of the monomers as well as the polymerization conditions. The results revealed that the reactions between triangular triamines and rod-like PMDA tended to form six-membered ring units, which were then extended to yield polyimide crosslinking networks, reflected by the complete disappearance of the endgroup signals in the FTIR and (13)C CP MAS spectra, the significantly high thermal stability, large accessible surface area (818 cm(2) g(-1)) and narrow pore size distribution centered at 4-8 angstrom. On the contrary, the low reactivity and steric bulky naphthyl group of the NTDA monomer led to the generation of branched or hyperbranched oligomers, which were further mutually crosslinked at a high temperature to produce the polyimde networks. In this way, a small amount of unreacted groups unavoidably remained, and the polymers exhibited a heterogeneous topological architecture, a broad pore size distribution and a low surface area of only 232 cm(2) g(-1). The influences of synthetic control and monomer structures on the pore morphologies and properties are investigated.