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个人信息Personal Information
教授
博士生导师
硕士生导师
性别：男
毕业院校：中国科学院长春应用化学研究所
学位：博士
所在单位：化工学院
学科：高分子材料. 高分子化学与物理
办公地点：西部校区化工实验楼A座206
联系方式：0411-84986096,13591156428
电子邮箱：zgwang@dlut.edu.cn
Two New Metal-Organic Frameworks with Mixed Ligands of Carboxylate and Bipyridine Synthesis, Crystal Structure, and Sensing for Methanol
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论文类型：期刊论文
发表时间：2010-12-01
发表刊物：CRYSTAL GROWTH & DESIGN
收录刊物：SCIE、EI、Scopus
卷号：10
期号：12
页面范围：5020-5023
ISSN号：1528-7483
摘要：Two new mixed ligand metal organic frameworks, [Cu-2(OH)(2,2' bipy)(2)(BTC) 2H(2)O](n) (1) and [Co(4 4' bipy) (m BDC)](n) (2) have been synthesized by hydrothermal reaction of Cu(COO)(2) H2O with 1 3 5 benzenetricarboxylic acid (H3BTC) and 2 2' bipyridine and of Co(NO3)(2) 6H(2)O with 1 3 benzenedicarboxylic acid (m H2BDC) and 4,4' bipyridine respectively They were characterized by single crystal X ray diffraction analysis powder XRD, elemental analysis TGA, and IR spectroscopy The adsorption characteristics of compounds 1 and 2 for methanol were investigated in situ with a quartz crystal microbalance (QCM) which indicated that they were highly sensitive to methanol at room temperature