Release Time:2019-03-12  Hits:

Indexed by: Journal Article

Date of Publication: 2017-08-17

Journal: ADVANCED SYNTHESIS & CATALYSIS

Included Journals: Scopus、SCIE

Volume: 359

Issue: 16

Page Number: 2723-2728

ISSN: 1615-4150

Key Words: allyl pinacolborate; allylation; catalysis; palladium; regioselectivity

Abstract: The palladium-catalyzed regioselective allylation reaction between chloromethyl(hetero)arenes and allyl pinacolborate is reported in this work. Chloromethylarenes smoothly reacted with allyl pinacolborate, producing para-allylated dearomatization products or para-allylated arenes in satisfactory to good yields. 2-(Chloromethyl)thiophenes and 2-(chloromethyl)furans bearing substituents on the 5-positions also smoothly reacted with allyl pinacolborate, producing the 5-allylated dearomatization products in satisfactory yields.