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Indexed by:期刊论文

Date of Publication:2017-08-17

Journal:ADVANCED SYNTHESIS & CATALYSIS

Included Journals:SCIE、Scopus

Volume:359

Issue:16

Page Number:2723-2728

ISSN No.:1615-4150

Key Words:allyl pinacolborate; allylation; catalysis; palladium; regioselectivity

Abstract:The palladium-catalyzed regioselective allylation reaction between chloromethyl(hetero)arenes and allyl pinacolborate is reported in this work. Chloromethylarenes smoothly reacted with allyl pinacolborate, producing para-allylated dearomatization products or para-allylated arenes in satisfactory to good yields. 2-(Chloromethyl)thiophenes and 2-(chloromethyl)furans bearing substituents on the 5-positions also smoothly reacted with allyl pinacolborate, producing the 5-allylated dearomatization products in satisfactory yields.