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Indexed by:期刊论文

Date of Publication:2017-06-02

Journal:JOURNAL OF ORGANIC CHEMISTRY

Included Journals:SCIE、EI、PubMed、Scopus

Volume:82

Issue:11

Page Number:5974-5980

ISSN No.:0022-3263

Abstract:Palladium-catalyzed remote sp(2)-sp(3) coupling reaction of chloromethylarenes with allyltrimethoxysilane is described in this work. The allylation reaction regioselectively occurred on the para-positions of 1-(chloromethyl)naphthalenes and benzyl chlorides to form new C(sp(2)) C(sp(3)) bonds. The reaction proceeds smoothly under mild conditions to produce allyl arenes in moderate to excellent yields.