Release Time:2019-03-12  Hits:

Indexed by: Journal Article

Date of Publication: 2017-06-02

Journal: JOURNAL OF ORGANIC CHEMISTRY

Included Journals: Scopus、PubMed、EI、SCIE

Volume: 82

Issue: 11

Page Number: 5974-5980

ISSN: 0022-3263

Abstract: Palladium-catalyzed remote sp(2)-sp(3) coupling reaction of chloromethylarenes with allyltrimethoxysilane is described in this work. The allylation reaction regioselectively occurred on the para-positions of 1-(chloromethyl)naphthalenes and benzyl chlorides to form new C(sp(2)) C(sp(3)) bonds. The reaction proceeds smoothly under mild conditions to produce allyl arenes in moderate to excellent yields.