Release Time:2019-03-12  Hits:

Indexed by: Journal Article

Date of Publication: 2017-04-01

Journal: CHINESE CHEMICAL LETTERS

Included Journals: CSCD、SCIE

Volume: 28

Issue: 4

Page Number: 900-904

ISSN: 1001-8417

Key Words: 5-Vinyl-2-norbornene; Diels-Alder reaction; Cyclopentadiene; 1,3-Butadiene; Supercritical carbon dioxide

Abstract: An efficient method for the synthesis of 5-vinyl-2-norbornene from cyclopentadiene and 1,3-butadiene was developed. The Diels-Alder reaction of cyclopentadiene with 1,3-butadiene proceeded smoothly in supercritical carbon dioxide in the absence of any polymerization inhibitor to produce the corresponding 5-vinyl-2-norbornene in satisfactory yield with high selectivity. (C) 2016 Chinese Chemical Society and Institute of Materia Medica, Chinese Academy of Medical Sciences. Published by Elsevier B.V. All rights reserved.