Release Time:2019-03-12  Hits:

Indexed by: Journal Article

Date of Publication: 2017-02-01

Journal: ASIAN JOURNAL OF ORGANIC CHEMISTRY

Included Journals: SCIE

Volume: 6

Issue: 2

Page Number: 177-183

ISSN: 2193-5807

Key Words: arenes; carbon dioxide fixation; multicomponent reactions; palladium; silanes

Abstract: The palladium-catalyzed three-component coupling of either (chloromethyl)arenes or (chloromethyl)heteroarenes with allyltrimethoxysilane and carbon dioxide (i.e., a carboxylative Hiyama coupling reaction) successfully produced ,alpha,beta-unsaturated esters in satisfactory to good yields. This reaction proceeded smoothly under mild conditions in the presence of palladium nanoparticles (NPs). A reaction mechanism, which includes the formation of an pi-allylpalladium chloride intermediate, has been proposed.