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Selective hydrogenation of the CvC bond in alpha,beta-unsaturated aldehydes and ketones over ultra-small Pd-Au clusters

Release Time:2019-03-13  Hits:

Indexed by: Journal Article

Date of Publication: 2016-11-28

Journal: NANOSCALE

Included Journals: Scopus、EI、SCIE

Volume: 8

Issue: 44

Page Number: 18626-18629

ISSN: 2040-3364

Abstract: Pd-Au clusters of 1.8 nm preferentially catalyzed the hydrogenation of the CvC bond in alpha,beta-unsaturated aldehydes and ketones with a selectivity of similar to 99%, primarily because of the unique electronic properties and isolated Pd ensembles on the ultra-small alloyed particles.

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