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Selective hydrogenation of the CvC bond in alpha,beta-unsaturated aldehydes and ketones over ultra-small Pd-Au clusters

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Indexed by:期刊论文

Date of Publication:2016-11-28

Journal:NANOSCALE

Included Journals:SCIE、EI、Scopus

Volume:8

Issue:44

Page Number:18626-18629

ISSN No.:2040-3364

Abstract:Pd-Au clusters of 1.8 nm preferentially catalyzed the hydrogenation of the CvC bond in alpha,beta-unsaturated aldehydes and ketones with a selectivity of similar to 99%, primarily because of the unique electronic properties and isolated Pd ensembles on the ultra-small alloyed particles.

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