Release Time:2019-03-09  Hits:

Indexed by: Journal Papers

Date of Publication: 2015-12-02

Journal: TETRAHEDRON LETTERS

Included Journals: Scopus、SCIE

Volume: 56

Issue: 48

Page Number: 6747-6750

ISSN: 0040-4039

Key Words: Palladium nanoparticles; Carbon dioxide; Carboxylative coupling

Abstract: The palladium-catalyzed three-component coupling reaction of five-membered (chloromethyl) heteroarenes, allyltributylstannane, and carbon dioxide (carboxylative Stille coupling reaction) was successfully conducted to produce beta,gamma-unsaturated esters in satisfactory to good yields. The carboxylative Stille coupling reaction occurred smoothly under mild conditions in the presence of palladium nanopartides through the formation of pi-allylpalladium chloride intermediates. (C) 2015 Elsevier Ltd. All rights reserved.