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Indexed by:期刊论文

Date of Publication:2014-01-17

Journal:ORGANIC LETTERS

Included Journals:SCIE、Scopus

Volume:16

Issue:2

Page Number:620-623

ISSN No.:1523-7060

Abstract:A novel and highly efficient Cu-catalyzed C-H amination of the monofunctionalized hydrofullerenes for the synthesis of 1,4-difunctional fullerenes has been reported. A new series of 1,4-fullerene derivatives having various monoamine addends were synthesized in good to high yields under mild reaction conditions. The controlled experiments revealed that the reaction proceeds through the formation of a fullerene monoradical as a key intermediate followed by coupling with an amine radical.