Release Time:2019-03-09  Hits:

Indexed by: Journal Article

Date of Publication: 2013-08-02

Journal: ORGANIC LETTERS

Included Journals: Scopus、SCIE

Volume: 15

Issue: 15

Page Number: 4030-4033

ISSN: 1523-7060

Abstract: An efficient and highly selective Co-catalyzed radical cycloaddition of [60]fullerene with active dibromides for the synthesis of three-, five-, six-, and seven-membered carbocycle-fused fullerene monoadducts has been reported. The controlled experiments unambiguously disclosed that the reaction proceeds through the formation of a fullerene monoradical as a key intermediate.