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Co-Catalyzed Radical Cycloaddition of [60]Fullerene with Active Dibromides: Selective Synthesis of Carbocycle-Fused Fullerene Monoadducts

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Indexed by:期刊论文

Date of Publication:2013-08-02

Journal:ORGANIC LETTERS

Included Journals:SCIE、Scopus

Volume:15

Issue:15

Page Number:4030-4033

ISSN No.:1523-7060

Abstract:An efficient and highly selective Co-catalyzed radical cycloaddition of [60]fullerene with active dibromides for the synthesis of three-, five-, six-, and seven-membered carbocycle-fused fullerene monoadducts has been reported. The controlled experiments unambiguously disclosed that the reaction proceeds through the formation of a fullerene monoradical as a key intermediate.

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