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NaOH-Catalyzed Dimerization of Monofunctionalized Hydrofullerenes: Transition-Metal-Free, General, and Efficient Synthesis of Single-Bonded [60]Fullerene Dimers

Release Time:2019-03-09  Hits:

Indexed by: Journal Article

Date of Publication: 2012-07-06

Journal: ORGANIC LETTERS

Included Journals: Scopus、SCIE

Volume: 14

Issue: 13

Page Number: 3466-3469

ISSN: 1523-7060

Abstract: Unprecedented, transition-metal-free NaOH-catalyzed homo- and cross-dimerizations of monofunctionalized hydrofullerenes are reported. Various single-bonded fullerene dimers were synthesized under mild reaction conditions with remarkably high yields. The use of a NaOH catalyst combined with tetrahydrofuran as a cosolvent under an air atmosphere is critical in achieving highly efficient catalytic dimerization.

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