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NaOH-Catalyzed Dimerization of Monofunctionalized Hydrofullerenes: Transition-Metal-Free, General, and Efficient Synthesis of Single-Bonded [60]Fullerene Dimers

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Indexed by:期刊论文

Date of Publication:2012-07-06

Journal:ORGANIC LETTERS

Included Journals:SCIE、Scopus

Volume:14

Issue:13

Page Number:3466-3469

ISSN No.:1523-7060

Abstract:Unprecedented, transition-metal-free NaOH-catalyzed homo- and cross-dimerizations of monofunctionalized hydrofullerenes are reported. Various single-bonded fullerene dimers were synthesized under mild reaction conditions with remarkably high yields. The use of a NaOH catalyst combined with tetrahydrofuran as a cosolvent under an air atmosphere is critical in achieving highly efficient catalytic dimerization.

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