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Suzuki reaction of bromoallenes with arylboronic acids using an air-stable palladium complex Pd(Ph2PCH2CO2)(2) as a precatalyst

Release Time:2019-03-09  Hits:

Indexed by: Journal Article

Date of Publication: 2010-06-01

Journal: CHINESE CHEMICAL LETTERS

Included Journals: CSCD、ISTIC、SCIE

Volume: 21

Issue: 6

Page Number: 641-645

ISSN: 1001-8417

Key Words: Suzuki reaction; Bromoallene; Palladium complex

Abstract: Suzuki reaction of bromoallenes with arylboronic acids was successfully performed by using an air-stable hemilabile P-O coordinated cyclopalladated complex Pd(Ph2PCH2CO2)(2) as a precatalyst, and the corresponding coupling products were obtained in satisfactory to excellent yields. All products are unknown compounds which were characterized by H-1 NMR, C-13 NMR, IR, and HRMS. (C) 2010 Xiu Juan Feng. Published by Elsevier B.V. on behalf of Chinese Chemical Society. All rights reserved.

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