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Carbocycle synthesis through facile and efficient palladium-catalyzed allylative de-aromatization of naphthalene and phenanthrene allyl chlorides

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Indexed by:期刊论文

Date of Publication:2008-07-01

Journal:ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Included Journals:SCIE、EI、PubMed

Volume:47

Issue:23

Page Number:4366-4369

ISSN No.:1433-7851

Key Words:de-aromatization; naphthalenes; palladium; phenanthrenes; synthetic methods

Abstract:(Chemical Equation Presented) Ring of truth: The palladium-catalyzed reaction of allyltributylstannane with naphthalene or phenanthrene derivatives bearing an allyl chloride group proceeds smoothly to provide de-aromatized products with unique structures (see scheme). These products are very stable and can be used as intermediates to give fused-ring systems. © 2008 Wiley-VCH Verlag GmbH & Co. KGaA.

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