Release Time:2019-03-10  Hits:

Indexed by: Journal Article

Date of Publication: 2008-07-01

Journal: ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Included Journals: PubMed、EI、SCIE

Volume: 47

Issue: 23

Page Number: 4366-4369

ISSN: 1433-7851

Key Words: de-aromatization; naphthalenes; palladium; phenanthrenes; synthetic methods

Abstract: (Chemical Equation Presented) Ring of truth: The palladium-catalyzed reaction of allyltributylstannane with naphthalene or phenanthrene derivatives bearing an allyl chloride group proceeds smoothly to provide de-aromatized products with unique structures (see scheme). These products are very stable and can be used as intermediates to give fused-ring systems. © 2008 Wiley-VCH Verlag GmbH & Co. KGaA.