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论文类型：会议论文

发表时间：2014-08-19

页面范围：1

关键字：complexes;inspired;attributed;extraordinary;pendent;bases;consequently;Hydrogen;clean;hydrogenation;

摘要：Hydrogen is particularly important as a clean fuel of the future.Efficient storage of hydrogen has consequently attracted much more attention.Herein,we introduce that the water-soluble and bio-inspired Ir complexes 1,2,and 3 are efficient catalysts for hydrogen storage by catalyzing the interconversion of H_2/CO_2 and HCOOH(Fig.1).~(1-4)The extraordinary activity of these complexes are attributed to the-OH moieties on the ligand which serve as pendent bases and strong electron donors after deprotonation under basic conditions.