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个人信息Personal Information
教授
博士生导师
硕士生导师
性别：男
毕业院校：日本东北大学
学位：博士
所在单位：化工学院盘锦分院
办公地点：精细化工国家重点实验室E504
电子邮箱：mingbao@dlut.edu.cn
Carbonylative Sonogashira Coupling of Aryl Iodides with Terminal Alkynes Catalyzed by Palladium Nanoparticles
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论文类型：期刊论文
发表时间：2018-03-01
发表刊物：JOURNAL OF THE CHINESE CHEMICAL SOCIETY
收录刊物：SCIE、CPCI-S
卷号：65
期号：3,SI
页面范围：337-345
ISSN号：0009-4536
关键字：Palladium nanoparticles; alpha,beta-Alkynyl ketones; Carbonylative Sonogashira coupling
摘要：A convenient and efficient method for the synthesis of a, beta-alkynyl ketones from the three-component coupling of aryl iodides, terminal alkynes, and carbon monoxide (carbonylative Sonogashira coupling reaction) is successfully developed. The carbonylative Sonogashira coupling reaction proceeded smoothly under mild conditions in the presence of palladium nanoparticles to produce the corresponding a, beta-alkynyl ketones in good to excellent yields.