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个人信息Personal Information
教授
博士生导师
硕士生导师
性别：男
毕业院校：日本东北大学
学位：博士
所在单位：化工学院盘锦分院
办公地点：精细化工国家重点实验室E504
电子邮箱：mingbao@dlut.edu.cn
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Palladium-Catalyzed sp(2)-sp(3) Coupling of Chloromethylarenes with Allyltrimethoxysilane: Synthesis of Allyl Arenes
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论文类型：期刊论文
发表时间：2017-06-02
发表刊物：JOURNAL OF ORGANIC CHEMISTRY
收录刊物：SCIE、EI、PubMed、Scopus
卷号：82
期号：11
页面范围：5974-5980
ISSN号：0022-3263
摘要：Palladium-catalyzed remote sp(2)-sp(3) coupling reaction of chloromethylarenes with allyltrimethoxysilane is described in this work. The allylation reaction regioselectively occurred on the para-positions of 1-(chloromethyl)naphthalenes and benzyl chlorides to form new C(sp(2)) C(sp(3)) bonds. The reaction proceeds smoothly under mild conditions to produce allyl arenes in moderate to excellent yields.