|
个人信息Personal Information
教授
博士生导师
硕士生导师
性别：男
毕业院校：日本东北大学
学位：博士
所在单位：化工学院盘锦分院
办公地点：精细化工国家重点实验室E504
电子邮箱：mingbao@dlut.edu.cn
Synthesis of 5-vinyl-2-norbornene through Diels-Alder reaction of cyclopentadiene with 1,3-butadiene in supercritical carbon dioxide
点击次数：
论文类型：期刊论文
发表时间：2017-04-01
发表刊物：CHINESE CHEMICAL LETTERS
收录刊物：SCIE、CSCD
卷号：28
期号：4
页面范围：900-904
ISSN号：1001-8417
关键字：5-Vinyl-2-norbornene; Diels-Alder reaction; Cyclopentadiene; 1,3-Butadiene; Supercritical carbon dioxide
摘要：An efficient method for the synthesis of 5-vinyl-2-norbornene from cyclopentadiene and 1,3-butadiene was developed. The Diels-Alder reaction of cyclopentadiene with 1,3-butadiene proceeded smoothly in supercritical carbon dioxide in the absence of any polymerization inhibitor to produce the corresponding 5-vinyl-2-norbornene in satisfactory yield with high selectivity. (C) 2016 Chinese Chemical Society and Institute of Materia Medica, Chinese Academy of Medical Sciences. Published by Elsevier B.V. All rights reserved.