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个人信息Personal Information
教授
博士生导师
硕士生导师
性别：男
毕业院校：日本东北大学
学位：博士
所在单位：化工学院盘锦分院
办公地点：精细化工国家重点实验室E504
电子邮箱：mingbao@dlut.edu.cn
Carboxylative Coupling of Chloromethyl(hetero)arenes with Allyltrimethoxysilane Catalyzed by Palladium Nanoparticles
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论文类型：期刊论文
发表时间：2017-02-01
发表刊物：ASIAN JOURNAL OF ORGANIC CHEMISTRY
收录刊物：SCIE
卷号：6
期号：2
页面范围：177-183
ISSN号：2193-5807
关键字：arenes; carbon dioxide fixation; multicomponent reactions; palladium; silanes
摘要：The palladium-catalyzed three-component coupling of either (chloromethyl)arenes or (chloromethyl)heteroarenes with allyltrimethoxysilane and carbon dioxide (i.e., a carboxylative Hiyama coupling reaction) successfully produced ,alpha,beta-unsaturated esters in satisfactory to good yields. This reaction proceeded smoothly under mild conditions in the presence of palladium nanoparticles (NPs). A reaction mechanism, which includes the formation of an pi-allylpalladium chloride intermediate, has been proposed.