包明
个人信息Personal Information
教授
博士生导师
硕士生导师
性别:男
毕业院校:日本东北大学
学位:博士
所在单位:化工学院盘锦分院
办公地点:精细化工国家重点实验室E504
电子邮箱:mingbao@dlut.edu.cn
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Rhodium-Catalyzed Oxidative Benzannulation of N-Pivaloylanilines with Internal Alkynes through Dual C-H Bond Activation: Synthesis of Highly Substituted Naphthalenes
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论文类型:期刊论文
发表时间:2016-11-22
发表刊物:Chemistry-An Asian Journal
收录刊物:SCIE、EI、PubMed、Scopus
卷号:11
期号:22
页面范围:3241-3250
ISSN号:1861-4728
关键字:benzannulation; naphthalene; N-pivaloylaniline; rhodium catalysis
摘要:An efficient method was developed for the synthesis of highly substituted naphthalenes through rhodium-catalyzed oxidative benzannulation of N-pivaloylanilines with internal alkynes. The benzannulation reaction proceeded smoothly through dual C-H bond activation to produce the corresponding highly substituted naphthalene products in satisfactory to good yields.