包明

个人信息Personal Information

教授

博士生导师

硕士生导师

性别:男

毕业院校:日本东北大学

学位:博士

所在单位:化工学院盘锦分院

办公地点:精细化工国家重点实验室E504

电子邮箱:mingbao@dlut.edu.cn

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Rhodium-Catalyzed Oxidative Benzannulation of N-Pivaloylanilines with Internal Alkynes through Dual C-H Bond Activation: Synthesis of Highly Substituted Naphthalenes

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论文类型:期刊论文

发表时间:2016-11-22

发表刊物:Chemistry-An Asian Journal

收录刊物:SCIE、EI、PubMed、Scopus

卷号:11

期号:22

页面范围:3241-3250

ISSN号:1861-4728

关键字:benzannulation; naphthalene; N-pivaloylaniline; rhodium catalysis

摘要:An efficient method was developed for the synthesis of highly substituted naphthalenes through rhodium-catalyzed oxidative benzannulation of N-pivaloylanilines with internal alkynes. The benzannulation reaction proceeded smoothly through dual C-H bond activation to produce the corresponding highly substituted naphthalene products in satisfactory to good yields.