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个人信息Personal Information
教授
博士生导师
硕士生导师
性别：男
毕业院校：日本东北大学
学位：博士
所在单位：化工学院盘锦分院
办公地点：精细化工国家重点实验室E504
电子邮箱：mingbao@dlut.edu.cn
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Rh(III)-Catalyzed Regioselective Functionalization of C-H Bonds of Naphthylcarbamates for Oxidative Annulation with Alkynes
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论文类型：期刊论文
发表时间：2014-09-19
发表刊物：ORGANIC LETTERS
收录刊物：SCIE、Scopus
卷号：16
期号：18
页面范围：4830-4833
ISSN号：1523-7060
摘要：A Rh(III)-catalyzed highly efficient and regioselective functionalization of diverse C-H bonds of naphthylcarbamates for oxidative annulation with alkynes has been developed. The annulation with a neutral rhodium catalyst system proceeds through peri C-H bond functionalization of arylcarbamates to give benzoquinoline derivatives, while with a cationic rhodium catalyst system it proceeds through ortho C-H functionalization of arylcarbamates to furnish benzoindole derivatives.